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propylene carbonate : ウィキペディア英語版
propylene carbonate

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Propylene carbonate (often abbreviated PC) is an organic compound with the formula CH3C2H3O2CO. It is a carbonate ester derived from propylene glycol.〔(WebBook page for propylene carbonate )〕 This colorless and odorless liquid is useful as a polar, aprotic solvent.〔 Propylene carbonate is chiral but is used exclusively as the racemic mixture.
==Preparation==
Although many organic carbonates are produced using phosgene, propylene and ethylene carbonates are exceptions. They are mainly prepared by the carbonation of the epoxides:〔
:CH3CHCH2O + CO2 → CH3C2H3O2CO
The process is particularly attractive since the production of these epoxides consumes carbon dioxide. Thus this reaction is a good example of a green process. The corresponding reaction of 1,2-propanediol with phosgene is complex, yielding not only propylene carbonate but also oligomeric products.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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